Reciprocal relations between kinetic curves

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Reciprocal relations between kinetic curves

We study coupled irreversible processes. For linear or linearized kinetics with microreversibility, ẋ=Kx, the kinetic operator K is symmetric in the entropic inner product. This form of Onsager’s reciprocal relations implies that the shift in time, exp(Kt), is also a symmetric operator. This generates the reciprocity relations between the kinetic curves. For example, for the Master equation, if...

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ژورنال

عنوان ژورنال: EPL (Europhysics Letters)

سال: 2011

ISSN: 0295-5075,1286-4854

DOI: 10.1209/0295-5075/93/20004